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Generating terahertz radiation from water makes ÌÇÐÄ´«Ã½˜the impossible, possibleÌÇÐÄ´«Ã½™

Researchers use lasers to generate terahertz pulses via interaction with a target. In this case, the target was an extremely thin water filmÌÇÐÄ´«Ã½”approximately 200 microns or about the thickness of two pieces of paperÌÇÐÄ´«Ã½”created using water suspended between two aluminum wires. (photo credit: Brandon Dube)

Xi-Cheng Zhang has worked for nearly a decade to solve a scientific puzzle that many in the research community believed to be impossible: producing terahertz wavesÌÇÐÄ´«Ã½”a form of electromagnetic radiation in the far infrared frequency rangeÌÇÐÄ´«Ã½”from liquid water.

Now, as reported in a paper published in , researchers at the University of Rochester have ÌÇÐÄ´«Ã½œmade the impossible, possible,ÌÇÐÄ´«Ã½� says Zhang, the M. Parker Givens Professor of Optics. ÌÇÐÄ´«Ã½œFiguring out how to generate terahertz waves from liquid water is a fundamental breakthrough because water is such an important element in the human body and on Earth.ÌÇÐÄ´«Ã½�

have attracted increased attention recently because of their ability to nondestructively pass through solid objects, including those made of cloth, paper, wood, plastic, and ceramics, and produce images of the interiors of the objects. Additionally, the energy of a terahertz photon is weaker than an x-ray photon. Unlike x-rays, terahertz waves are non-ionizingÌÇÐÄ´«Ã½”they do not have enough energy to remove an electron from an atomÌÇÐÄ´«Ã½”so they do not have the same harmful effects on human tissue and DNA.

Because of these abilities, terahertz waves have unique applications in imaging and spectroscopyÌÇÐÄ´«Ã½”everything from discovering bombs in suspicious packages, to identifying murals hidden beneath coats of paint, to detecting tooth decay.

ÌÇÐÄ´«Ã½œTerahertz waves have a capacity to see through clothing, which is why you have these sub-terahertz body scanners at airports,ÌÇÐÄ´«Ã½� Zhang says. ÌÇÐÄ´«Ã½œThese waves can help to identify if an object is explosive, chemical, or biological, even if they canÌÇÐÄ´«Ã½™t tell exactly what the object is.ÌÇÐÄ´«Ã½�

ZhangÌÇÐÄ´«Ã½™s research group uses lasers to generate terahertz pulses via interaction with a target. In this case, the target is an extremely thin film of waterÌÇÐÄ´«Ã½”approximately 200 microns or about the thickness of two pieces of paperÌÇÐÄ´«Ã½”created using water suspended by surface tension between two aluminum wires. Researchers focus a laser into the water film, which acts as an emitter for the terahertz radiation output.

scientific diagram showing a pump beam going through a water film
The experimental set-up used to generate terahertz waves from liquid water. Researchers focus the optical pump beam into the water film and use a series of filters and off-axis parabolic mirrors (OAPMs) to detect the terahertz signal and block any other light waves simultaneously generated from the water film.

Previous researchers have generated terahertz waves from targets of solid crystals, metals, air plasma, and water vapor, but, until now, liquid water has proved elusive.

ÌÇÐÄ´«Ã½œWater was considered the enemy of terahertz waves because of waterÌÇÐÄ´«Ã½™s strong absorption,ÌÇÐÄ´«Ã½� Zhang says. ÌÇÐÄ´«Ã½œWe always tried to avoid water, but it is a surprisingly efficient terahertz source.ÌÇÐÄ´«Ã½�

In fact, when researchers measured the terahertz waves generated by the water, they found they were 1.8 times stronger than the terahertz waves generated from air plasma under comparable experimental conditions.

Because water is such a strong absorber, however, many people in the research community believed it would be impossible to use water as a target. Zhang himself has spent years attempting a solution, and he found a likewise stalwart in Qi Jin, now a PhD candidate in optics at Rochester, and the lead author on the paper.

ÌÇÐÄ´«Ã½œAlmost everybody thought we wouldnÌÇÐÄ´«Ã½™t be able to get a signal from water,ÌÇÐÄ´«Ã½� Jin says. ÌÇÐÄ´«Ã½œAt first, I didnÌÇÐÄ´«Ã½™t believe it either.ÌÇÐÄ´«Ã½�

One of the challenges was creating a film of water thin enough that the terahertz photons generated by the laser beam would not be absorbed, but thick enough to withstand the laserÌÇÐÄ´«Ã½™s energy.

Along with Yiwen E, a postdoctoral associate in ZhangÌÇÐÄ´«Ã½™s research group, Jin spent months optimizing the thickness of the water film and the incident angle, intensity, and pulse duration of the laser beam.

ÌÇÐÄ´«Ã½œWe increased the thickness of the water a little bit, and gradually increased the laser, and just kept trying until we could make it work,ÌÇÐÄ´«Ã½� Jin says.  ÌÇÐÄ´«Ã½œWater is one of the richest resources on Earth, so it was really important for us to be able to generate these waves from water. There were many times I wanted to give up on this, but people in the lab kept encouraging me.ÌÇÐÄ´«Ã½�

Zhang agrees: ÌÇÐÄ´«Ã½œI always tell my students and researchers here: if you try something, you might not get the result you wanted. But if you never try it, you definitely wonÌÇÐÄ´«Ã½™t get it.ÌÇÐÄ´«Ã½�

The research was sponsored by grants from the Army Research Office.